Acids
Acids are substances that exhibit sour taste, turn blue litmus paper red, and react with metals to produce hydrogen gas. They are important in chemistry, industry, and biological processes.
Acids are substances that exhibit sour taste, turn blue litmus paper red, and react with metals to produce hydrogen gas. They are important in chemistry, industry, and biological processes.
Arrhenius Definition: An acid is a substance that produces hydrogen ions (H⁺) when dissolved in water.
Example: $$ \text{HCl}_{(aq)} \rightarrow \text{H}^+_{(aq)} + \text{Cl}^-_{(aq)} $$
Brønsted–Lowry Definition: An acid is a proton (H⁺) donor, while a base is a proton acceptor.
Example: $$ \text{NH}_3 + \text{H}_2\text{O} \rightarrow \text{NH}_4^+ + \text{OH}^- $$
Here, water acts as an acid because it donates a proton to ammonia.
Lewis Definition: An acid is a substance that can accept a pair of electrons to form a covalent bond.
Example: $$ \text{BF}_3 + \text{NH}_3 \rightarrow \text{F}_3\text{B–NH}_3 $$
1. Based on Source
2. Based on Concentration
3. Based on Strength
Note: HCN (hydrogen cyanide) is a weak acid because it partially ionizes in water — only a small fraction of its molecules donate protons (H⁺) to form hydronium ions (H₃O⁺). The ionization can be represented as: $$ \text{HCN}_{(aq)} + \text{H}_2\text{O}_{(l)} \rightleftharpoons \text{H}_3\text{O}^+_{(aq)} + \text{CN}^-_{(aq)} $$
| Organic Acid | Source |
|---|---|
| Citric Acid | Citrus fruits (orange, lemon) |
| Acetic Acid | Vinegar |
| Lactic Acid | Sour milk and muscles after exercise |
| Tartaric Acid | Tamarind and grapes |
| Formic Acid | Ants and stinging nettles |
| Oxalic Acid | Spinach and rhubarb leaves |
| Malic Acid | Apples and pears |
| Ascorbic Acid (Vitamin C) | Oranges, lemons, and tomatoes |
| Benzoic Acid | Preservatives and cranberries |
| Stearic Acid | Animal fats and vegetable oils |
| Butyric Acid | Butter and cheese |
| Uric Acid | Waste product in urine |
| Name of Acid | Chemical Formula |
|---|---|
| Hydrochloric Acid | HCl |
| Nitric Acid | HNO₃ |
| Sulfuric Acid | H₂SO₄ |
| Phosphoric Acid | H₃PO₄ |
| Carbonic Acid | H₂CO₃ |
| Hydrofluoric Acid | HF |
| Hydrobromic Acid | HBr |
| Hydroiodic Acid | HI |
| Boric Acid | H₃BO₃ |
| Chromic Acid | H₂CrO₄ |
| Perchloric Acid | HClO₄ |
| Silicic Acid | H₂SiO₃ |
The basicity of an acid is defined as the number of hydrogen ions (H⁺) that one molecule of the acid can donate or replace in a chemical reaction. In other words, it is the number of ionizable hydrogen atoms present in one molecule of an acid. The basicity of an acid depends on its molecular structure and the number of replaceable hydrogen atoms attached to oxygen.
For example: $$ \text{HCl} \rightarrow \text{H}^+ + \text{Cl}^- \quad (\text{Monobasic}) $$ $$ \text{H}_2\text{SO}_4 \rightarrow 2\text{H}^+ + \text{SO}_4^{2-} \quad (\text{Dibasic}) $$ $$ \text{H}_3\text{PO}_4 \rightarrow 3\text{H}^+ + \text{PO}_4^{3-} \quad (\text{Tribasic}) $$
| Acid Name | Formula | Basicity |
| Hydrochloric acid | HCl | 1 (Monobasic) |
| Nitric acid | HNO₃ | 1 (Monobasic) |
| Acetic acid | CH₃COOH | 1 (Monobasic) |
| Hydrofluoric acid | HF | 1 (Monobasic) |
| Hydrobromic acid | HBr | 1 (Monobasic) |
| Sulfuric acid | H₂SO₄ | 2 (Dibasic) |
| Carbonic acid | H₂CO₃ | 2 (Dibasic) |
| Thiosulfuric acid | H₂S₂O₃ | 2 (Dibasic) |
| Phosphoric acid | H₃PO₄ | 3 (Tribasic) |
| Boric acid | H₃BO₃ | 3 (Tribasic) |
| Arsenic acid | H₃AsO₄ | 3 (Tribasic) |
| Silicic acid | H₄SiO₄ | 4 (Tetrabasic) |