Acids, bases and salts
Acids

Acids are substances that exhibit sour taste, turn blue litmus paper red, and react with metals to produce hydrogen gas. They are important in chemistry, industry, and biological processes.

Definitions of Acids

Arrhenius Definition: An acid is a substance that produces hydrogen ions (H⁺) when dissolved in water.
Example: $$ \text{HCl}_{(aq)} \rightarrow \text{H}^+_{(aq)} + \text{Cl}^-_{(aq)} $$

Brønsted–Lowry Definition: An acid is a proton (H⁺) donor, while a base is a proton acceptor.
Example: $$ \text{NH}_3 + \text{H}_2\text{O} \rightarrow \text{NH}_4^+ + \text{OH}^- $$
Here, water acts as an acid because it donates a proton to ammonia.

Lewis Definition: An acid is a substance that can accept a pair of electrons to form a covalent bond.
Example: $$ \text{BF}_3 + \text{NH}_3 \rightarrow \text{F}_3\text{B–NH}_3 $$

Classification of Acids

1. Based on Source

2. Based on Concentration

3. Based on Strength

Common Organic acids
Organic Acid Source
Citric AcidCitrus fruits (orange, lemon)
Acetic AcidVinegar
Lactic AcidSour milk and muscles after exercise
Tartaric AcidTamarind and grapes
Formic AcidAnts and stinging nettles
Oxalic AcidSpinach and rhubarb leaves
Malic AcidApples and pears
Ascorbic Acid (Vitamin C)Oranges, lemons, and tomatoes
Benzoic AcidPreservatives and cranberries
Stearic AcidAnimal fats and vegetable oils
Butyric AcidButter and cheese
Uric AcidWaste product in urine
Common Inorganic Acids
Name of Acid Chemical Formula
Hydrochloric AcidHCl
Nitric AcidHNO₃
Sulfuric AcidH₂SO₄
Phosphoric AcidH₃PO₄
Carbonic AcidH₂CO₃
Hydrofluoric AcidHF
Hydrobromic AcidHBr
Hydroiodic AcidHI
Boric AcidH₃BO₃
Chromic AcidH₂CrO₄
Perchloric AcidHClO₄
Silicic AcidH₂SiO₃
Basicity of an Acid

The basicity of an acid is defined as the number of hydrogen ions (H⁺) that one molecule of the acid can donate or replace in a chemical reaction. In other words, it is the number of ionizable hydrogen atoms present in one molecule of an acid. The basicity of an acid depends on its molecular structure and the number of replaceable hydrogen atoms attached to oxygen.

For example: $$ \text{HCl} \rightarrow \text{H}^+ + \text{Cl}^- \quad (\text{Monobasic}) $$ $$ \text{H}_2\text{SO}_4 \rightarrow 2\text{H}^+ + \text{SO}_4^{2-} \quad (\text{Dibasic}) $$ $$ \text{H}_3\text{PO}_4 \rightarrow 3\text{H}^+ + \text{PO}_4^{3-} \quad (\text{Tribasic}) $$

Acids and Their Basicity
Acid Name Formula Basicity
Hydrochloric acidHCl1 (Monobasic)
Nitric acidHNO₃1 (Monobasic)
Acetic acidCH₃COOH1 (Monobasic)
Hydrofluoric acidHF1 (Monobasic)
Hydrobromic acidHBr1 (Monobasic)
Sulfuric acidH₂SO₄2 (Dibasic)
Carbonic acidH₂CO₃2 (Dibasic)
Thiosulfuric acidH₂S₂O₃2 (Dibasic)
Phosphoric acidH₃PO₄3 (Tribasic)
Boric acidH₃BO₃3 (Tribasic)
Arsenic acidH₃AsO₄3 (Tribasic)
Silicic acidH₄SiO₄4 (Tetrabasic)
Precautions in Handling Acids
Summary