Physical Properties of Bases
Bases and alkalis possess distinct physical characteristics that help identify them. These properties include:
- Most bases are solid at room temperature except ammonia, which is a gas.
- Soluble bases (alkalis) like NaOH and KOH dissolve in water to form slippery solutions.
- Bases have a bitter taste (though tasting is not recommended in the laboratory).
- Strong bases such as NaOH and KOH are corrosive to the skin and can cause burns.
- Many insoluble bases, such as Cu(OH)₂ and Fe(OH)₃, are colored compounds.
- Alkalis turn red litmus paper blue.
Chemical Properties of Bases
Bases and alkalis undergo various chemical reactions, such as neutralization and precipitation. Some common reactions include:
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Reaction with Acids (Neutralization):
Bases react with acids to form salt and water.
$$ \text{NaOH} + \text{HCl} \rightarrow \text{NaCl} + \text{H}_2\text{O} $$ $$ \text{Ca(OH)}_2 + \text{H}_2\text{SO}_4 \rightarrow \text{CaSO}_4 + 2\text{H}_2\text{O} $$ -
Reaction with Ammonium Salts:
Alkalis react with ammonium salts on heating to liberate ammonia gas.
$$ \text{NH}_4\text{Cl} + \text{NaOH} \rightarrow \text{NaCl} + \text{H}_2\text{O} + \text{NH}_3 $$ -
Reaction with Trioxocarbonates (CO₃²⁻):
Strong bases can decompose trioxocarbonates on heating to form metal oxides, water, and carbon dioxide.
$$ \text{Na}_2\text{CO}_3 + 2\text{NaOH} \xrightarrow{\text{Heat}} 2\text{Na}_2\text{O} + \text{H}_2\text{O} + \text{CO}_2 $$
$$ \text{CaCO}_3 + 2\text{NaOH} \xrightarrow{\text{Heat}} \text{Ca(OH)}_2 + \text{Na}_2\text{CO}_3 $$These reactions show that under certain conditions, strong alkalis can react with trioxocarbonates or bicarbonates, forming hydroxides or oxides along with the evolution of carbon dioxide.
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Reaction with Metal Ions (Precipitation Reaction):
Insoluble metal hydroxides are formed when alkalis react with soluble metal salts.
$$ \text{FeCl}_3 + 3\text{NaOH} \rightarrow \text{Fe(OH)}_3 + 3\text{NaCl} $$ $$ \text{CuSO}_4 + 2\text{NaOH} \rightarrow \text{Cu(OH)}_2 + \text{Na}_2\text{SO}_4 $$
Preparation of Bases
Bases and alkalis can be prepared through various methods depending on their solubility and reactivity.
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Reaction of Metals with Water:
Some reactive metals (like sodium and potassium) react with water to form their hydroxides and release hydrogen gas.
$$ 2\text{Na} + 2\text{H}_2\text{O} \rightarrow 2\text{NaOH} + \text{H}_2 $$ $$ 2\text{K} + 2\text{H}_2\text{O} \rightarrow 2\text{KOH} + \text{H}_2 $$ -
Reaction of Metal Oxides with Water:
Some metallic oxides dissolve in water to form alkalis.
$$ \text{CaO} + \text{H}_2\text{O} \rightarrow \text{Ca(OH)}_2 $$ $$ \text{Na}_2\text{O} + \text{H}_2\text{O} \rightarrow 2\text{NaOH} $$ -
Double Decomposition:
Soluble hydroxides can be obtained by reacting soluble salts of alkalis with soluble hydroxides.
$$ \text{FeCl}_3 + 3\text{NH}_4\text{OH} \rightarrow \text{Fe(OH)}_3 + 3\text{NH}_4\text{Cl} $$ $$ \text{CuSO}_4 + 2\text{NaOH} \rightarrow \text{Cu(OH)}_2 + \text{Na}_2\text{SO}_4 $$ -
By Electrolysis of Brine:
Sodium hydroxide is industrially prepared by the electrolysis of concentrated sodium chloride (brine) solution.
$$ 2\text{NaCl} + 2\text{H}_2\text{O} \xrightarrow{\text{Electrolysis}} 2\text{NaOH} + \text{Cl}_2 + \text{H}_2 $$