Organic chemistry I
Naming organic compounds

IUPAC Nomenclature is the systematic method used in naming organic compounds so that each compound has one unique and internationally accepted name. It removes ambiguity and ensures uniformity in chemical communication.

Rules for naming compounds

  1. Select the longest carbon chain containing the principal functional group.
  2. Number the chain from the end nearest to the functional group or the first substituent.
  3. Name the substituents (alkyl groups, halogens, nitro-group, etc.).
  4. Indicate the position of substituents using numbers (locants).
  5. If more than one substituent appears, use prefixes: di-, tri-, tetra-.
  6. Functional groups are given priority when naming.
  7. Write the name using the order: Prefix – Parent Name – Suffix (e.g., 2-methylpentan-3-ol).
  8. Use commas between numbers and hyphens between numbers and words.
  9. When naming compounds name in alphabetical order
Named examples
  1. penta-1,3-diene

    H   H       H   H
    |   |       |   |
    C = C — C = C — C — H
    |           |
    H           H
    

  2. But-2-ene

    H   H       H
    |   |       |
    C — C = C — C — H
    |       |   |
    H       H   H
    

  3. Methyl ethanoate

        H   
        |       
    H — C — C = O
        |   | 
        H   O — CH3
        CH3COOCH3
    

  4. 4- chloro pent-2-ene

        H   Cl  H   H   H
        |   |   |   |   |
    H — C — C — C = C — C — H
        |   |           |
        H   H           H
        CH3CH(Cl)CHCHCH3
    

  5. 2,2,5 trichloro hexane
        H   Cl  H   H   Cl  H
        |   |   |   |   |   |
    H — C — C — C — C — C — C — H
        |   |   |   |   |   |
        H   H   H   H   Cl  H
        CH3C(Cl)(Cl)CH2CH2CH(Cl)CH3
    
  6. butan-2-one
    H   O   H   H
    |  ||   |   |
    C — C — C — C — H
    |       |   |
    H       H   H
    CH3COCH2CH3
    
  7. 2,4 dichloro 2- methyl pentane

        H   CH3 H   H   H
        |   |   |   |   |
    H — C — C — C — C — C — H
        |   |   |   |   |
        H   Cl  H   Cl  H
     CH3C(Cl)(CH3)CH2CH(Cl)CH3
    
  8. Ethanol

        H   H
        |   |
    H - C - C - O - H
        |   |
        H   H
    
       CH3CH2OH
    
  9. Methoxymethane (Dimethyl ether)

        H       H
        |       |
    H - C - O - C - H
        |       |
        H       H
        CH3OCH3
       
  10. 1,1,2,2 - tetrachloroethane

        Cl  Cl
        |   |
    H - C - C - H
        |   |
        Cl  Cl
    
    CH(Cl)(Cl)CH(Cl)(Cl)
    
       
  11. 2-ethyl pentanoic acid

        H   H   H   C2H5  
        |   |   |   |   
    H — C — C — C — C — C = O
        |   |   |   |   |
        H   H   H   H   O — H
        CH3CH2CH2CH(C2H5)COOH
         

Summary