Physical properties of Oxygen
- It is neutral to litmus paper
- Oxygen gas liquefies at -183°C and solidifies at -225°C
- It is slightly soluble in water
- It is a colorless, odorless and tasteless gas
- It has about the same density as air
Chemical properties of oxygen
- Combustion: Hydrocarbons burn in oxygen to yield carbon (IV) oxide and water. $$CH_4 + 2O_2 \rightarrow CO_2 + 2H_2O $$
- Direct combination with metals: Oxygen conbines with most metals except gold, mercury and silver to yield basic oxides. $$ 4K + O_2 \rightarrow 2K_2O $$ $$ 2Ca + O_2 \rightarrow 2CaO $$ $$ 4Na + O_2 \rightarrow 2Na_2O $$ $$2Mg + O_2 \rightarrow 2MgO $$ The oxides of Sodium, potassium and calcium dissolve in water to form alkalis. $$ CaO + H_2O \rightarrow Ca(OH)_2 $$ $$ K_2O + H_2O \rightarrow 2KOH $$ $$ Na_2O + H_2O \rightarrow 2NaOH $$
- Direct combination with Non-metals: Oxygen combines with some non-metals like sulphur, carbon, nitrogen and phosphorus to produce acidic oxides. $$ S + O_2 \rightarrow SO_2 $$ $$ C + O_2 \rightarrow CO_2 $$ $$ P_4 + 3O_2 \rightarrow P_4O_6 $$ These acidic oxides dissolve in water to produce acids hence they are also called acid anhydrides. $$ SO_2 + H_2O \rightarrow H_2SO_3 $$ $$ CO_2 + H_2O \rightarrow H_2CO_3 $$ $$ P_4O_6 + 6H_2O \rightarrow 4H_3PO_4 $$
- Oxidation: Glucose is oxidized during respiration by oxygen to yield carbon (IV) oxide. $$ C_6H_{12}O_6 + 6O_2 \rightarrow 6CO_2 + 6H_2O $$
- Rusting: Oxygen reacts with iron in the presence of moisture to produce reddish brown iron (III) oxide. $$ 4Fe + 3O_2 + xH_2O \rightarrow 2Fe_2O_3.xH_2O $$
- Reaction with Nitrogen: Oxygen reacts with Nitrogen during lightning flashes to yield Nitrogen (II) oxide. $$ N_2 + O_2 \rightarrow 2NO $$
Test for oxygen
Place a glowing splint over a sample of the unknown gas. If the splint is rekindled, the gas is likely oxygen gas.
However, Dinitrogen (I) oxide \( N_2O \) also behaves similarly. The table below shows how these gas can be identified.
| Oxygen | Dinitrogen (I) oxide |
|---|---|
| It is Odourless | Gas has a pleasant smell |
| Slightly soluble in water | Fairly soluble in water |
| Reacts with Nitrogen (II) oxide to produce reddish brown fumes of Nitrogen (IV) oxide \( 2NO + O_2 \rightarrow 2NO_2 \) | No visible reaction with Nitrogen (II) oxide |
| No residual gas with heated copper | Residual gas, \( N_2 \) is formed with heated copper which absorbs oxygen |
Uses of oxygen
- Liquid oxygen is commonly used as rocket propellant in space exploration due to its ability to support combustion.
- Oxygen is used to aid breathing artificially.
- Oxygen combined with ethyne is used to produce oxy-ethyne flames which is used for cutting and melting metals.
- Oxygen is used in the manufacture of important chemical compounds like ethanoic acid, tetraoxosulphate (VI) acid, e.t.c
- Oxygen is employed in water treatment processes to eliminate impurities and enhance the quality of water.
- In metallurgical processes, oxygen is often used to refine and extract metals from their ores.
- In steel industry, oxygen is used to remove carbon, sulphur and phosphorus in the L-D process for steel production.