Qualitative Analysis I
Overview

In chemistry, qualitative analysis is the determination of the chemical composition of a sample. It encompasses a set of analytical chemistry techniques that provide nonnumerical information about a specimen.


Qualitative analysis can tell you whether an atom, ion, functional group, or compound is present or absent in a sample, but it doesn't provide information about its quantity. Quantification of a sample, in contrast, is called quantitative analysis.

Branches of qualitative analysis

There are two branches of qualitative analysis namely:

  1. Organic quantitative analysis
  2. Inorganic quantitative analysis

The basic testing procedure for identifying a compound is as follows:


Identification based on color or smell
Cation Observations Sample Salts
Ammonium (NH4+) Colorless or white crystals/powder
pungent smell of ammonia
Ammonium chloride (NH4Cl), Ammonium sulfate
(NH4 )2SO4
Potassium (K+), Sodium (Na+), Lead (Pb2+), Magnesium (Mg2+), Aluminum (Al3+), Zinc (Zn2+) Colorless or white crystals/powder Potassium, Calcium, Lead, Aluminum, Magnesium, Zinc salts
Iron (Fe2+) light green powder Ferrous sulfate (FeSO4 ), iron(II) chloride (Fecl2)
Iron (Fe3+) brown powder iron(III) chloride (Fecl3)
Flame test
Colour from flame test Likely ion
Brick red Ca²+
Crimson red Li2+
Lilac K2+
Golden yellow Na+
Deep greeen Cu2+
Blue Pb2+
Light green Ba2+
Summary