Nuclear chemistry I
Radioactive Decay

The decay a radioactive substance can undergo includes

Alpha (α) Decay

Alpha decay is the emission of an alpha particle (two protons and two neutrons, equivalent to a helium nucleus) from an unstable atomic nucleus. This process decreases the atomic number by 2 and the mass number by 4, forming a new element.

Characteristics
Examples

$$^{238}_{92}\text{U} \rightarrow ^{234}_{90}\text{Th} + ^{4}_{2}\text{He}$$ $$^{226}_{88}\text{Ra} \rightarrow ^{222}_{86}\text{Rn} + ^{4}_{2}\text{He}$$ $$^{210}_{84}\text{Po} \rightarrow ^{206}_{82}\text{Pb} + ^{4}_{2}\text{He}$$


Beta (β) Decay

Beta decay is the emission of a beta particle (an electron or positron) from the nucleus of a radioactive atom. In beta-minus (β⁻) decay, a neutron changes into a proton and an electron is emitted. In beta-plus (β⁺) decay, a proton changes into a neutron and a positron is emitted.

Characteristics
Examples

$$^{14}_{6}\text{C} \rightarrow ^{14}_{7}\text{N} + ^{0}_{-1}\text{e}$$ $$^{32}_{15}\text{P} \rightarrow ^{32}_{16}\text{S} + ^{0}_{-1}\text{e}$$ $$^{210}_{83}\text{Bi} \rightarrow ^{210}_{84}\text{Po} + ^{0}_{-1}\text{e}$$



Gamma Decay

Gamma decay is the emission of high-energy electromagnetic radiation (gamma rays) from the nucleus of an excited atom. It usually follows alpha or beta decay when the daughter nucleus is left in an excited state and releases energy to become stable. There is no change in mass number or atomic number during gamma emission.

Characteristics
Examples

$$^{60}_{27}\text{Co}^{*} \rightarrow ^{60}_{27}\text{Co} + \gamma$$ $$^{137}_{56}\text{Ba}^{*} \rightarrow ^{137}_{56}\text{Ba} + \gamma$$ $$^{234}_{90}\text{Th}^{*} \rightarrow ^{234}_{90}\text{Th} + \gamma$$

Nuclear Stability

Nuclear stability refers to the ability of an atomic nucleus to remain unchanged or resist disintegration over time. A stable nucleus does not spontaneously emit radiation, while an unstable nucleus tends to undergo radioactive decay to achieve a more stable state.

The stability of a nucleus depends mainly on the ratio of neutrons to protons (N/Z ratio). For lighter elements, stability is achieved when the number of neutrons and protons are nearly equal (N ≈ Z). However, for heavier elements, a higher number of neutrons is needed to offset the repulsive forces between the many protons.

Stable nuclei lie within a region called the band or belt of stability on a graph of neutrons versus protons. Nuclei outside this band are unstable and tend to undergo radioactive decay (such as alpha, beta, or gamma decay) to move into the stable region.

Factors affecting nuclear stability
Electron Capture

Electron capture is the process by which an unstable nucleus absorbs one of its own inner orbital electrons (usually from the K-shell), causing a proton in the nucleus to convert into a neutron. This process helps the nucleus move toward greater stability by reducing the proton-to-neutron ratio.

During electron capture, the captured electron combines with a proton to form a neutron and a neutrino. The neutrino is then ejected from the nucleus with very high speed but almost no mass. This process decreases the atomic number by one while the mass number remains unchanged.

The general nuclear equation for electron capture is:

$$ p^+ + e^- \rightarrow n + \nu_e $$

In symbolic form, for an element X:

$$ ^A_ZX + ^0_{-1}e \rightarrow ^A_{Z-1}Y + \nu_e $$

Examples:

$$ ^{40}_{19}K + ^0_{-1}e \rightarrow ^{40}_{18}Ar + \nu_e $$ $$ ^{7}_{4}Be + ^0_{-1}e \rightarrow ^{7}_{3}Li + \nu_e $$ $$ ^{55}_{26}Fe + ^0_{-1}e \rightarrow ^{55}_{25}Mn + \nu_e $$

Characteristics of Electron Capture

Summary