The kinetic theory of matter states that all particles in a substance are in constant motion and so possess kinetic energy . This motion is attributed to the particles' kinetic energy, which increases with higher temperatures. In a solid, particles vibrate in fixed positions; in a liquid, they move more freely; and in a gas, they move rapidly and independently. Changes in state are explained by the varying amounts of kinetic energy and intermolecular forces.
States of matter
- Solid: Particles are closely packed in a fixed arrangement, and they vibrate around fixed positions. They are held by strong cohesive forces with a low kinetic energy. They do not translate but can vibrate.
- Liquid: Particles are close together but can move past one another, allowing the substance to flow. The cohesive forces in liquids are less than that of solids. The particles in liquids have gained some kinetic energy hence they can translate from one point to another within a restricted space. They can translate, vibrate and rotate within a limit
- Gas: Particles are widely spaced and move freely, filling the shape and volume of their container. They are held by negligible cohesive forces. The particles in gases possess a greater kinetic energy compared to liquids hence their movement is random and at great speed. Gases also generate pressure when they bombard with themselves and the walls of their containing vessel.
- Plasma: A high-energy state where particles are ionized, commonly found in stars and lightning.
- Bose-Einstein Condensate: A state formed at extremely low temperatures where particles occupy the same quantum state.
- Fermionic Condensate: Similar to Bose-Einstein Condensate but involves fermions, a type of subatomic particle.
Others:
Differences
| Solid | Liquid | Gas |
|---|---|---|
| Definite shape | Indefinite shape | Indefinite shape |
| Definite volume | Definite volume | Indefinite volume |
| Molecules are closely packed | Molecules are close, but can move past one another | Molecules are widely spaced |
| Particles Vibrate and rotate about a fixed position | particles vibrate, rotate and move about a restriced space | particles move randomly and at great speed |
| cannot be easily compressed | cannot be easily compressed | Highly compressible |
| High density | Moderate density | Low density |
| Examples are Ice, Wood | Examples are Water, Oil | Examples are Air, Oxygen |
Change of state of matter
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Melting: The process by which a solid changes into a liquid due to an increase in temperature.
Imagine your favorite ice cream on a hot day. When the ice cream gets warm, it turns from a solid (ice) into a liquid (melted ice cream). This process is called melting.
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Sublimation: The transition from a solid directly to a gas without passing through the liquid state, often at low pressures.
Have you ever noticed how dry ice (frozen carbon dioxide) disappears without becoming a liquid? That's sublimation! It's when a substance goes directly from a solid to a gas without becoming a liquid in between.
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Evaporation: The conversion of a liquid into a vapor at the surface of the liquid, usually at temperatures below the boiling point.
Picture a wet puddle on the ground. As the sun shines on it, the water slowly disappears and turns into an invisible gas. This vanishing act is called evaporation.
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Boiling: The phase transition from a liquid to a gas throughout the entire mass of the liquid, typically at a specific temperature and pressure.
Think about boiling water for your favorite pasta. As the water gets hotter and hotter, you see bubbles forming and rising. That's boiling! It's when a liquid turns into vapor throughout the entire liquid, not just at the surface.
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Freezing: The process in which a liquid changes into a solid as it loses heat and reaches a lower temperature.
Remember the melted ice cream? Now, think about putting it in the freezer. The liquid ice cream slowly turns back into a solid. This process is freezing.
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Condensation: The transformation of a gas or vapor into a liquid as it loses heat, often forming dew or clouds.
After a hot shower, have you ever noticed water droplets forming on the bathroom mirror? That's condensation. It happens when a vapor (like steam from your shower) turns back into a liquid when it touches a cooler surface.
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Deposition: The transition of a gas directly into a solid without passing through the liquid state.
An example of deposition is the formation of frost on a cold surface.
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Ionization: The process in which atoms or molecules gain or lose electrons, turning into ions.
This change is often associated with high-energy processes such as exposure to intense heat or radiation.
Vapour pressure
Vapor pressure is the pressure exerted by a vapor (gas phase) in equilibrium with its liquid or solid phase at a given temperature. Condensation increases as vapor pressure increase.
- Temperature: As temperature increases, vapor pressure generally increases. Higher temperatures provide more energy for molecules to escape from the liquid phase into the vapor phase.
- Surface Area: A larger surface area enhances evaporation, leading to higher vapor pressure. This is why liquids in shallow containers evaporate more quickly than those in deep containers.
- Intermolecular Forces: Weaker intermolecular forces promote higher vapor pressure. Substances with weaker forces between molecules are more likely to transition into the vapor phase.
- Presence of Other Gases: Other gases above the liquid can impact vapor pressure. For instance, a decrease in atmospheric pressure decreases the boiling point, affecting vapor pressure.
Evaporation and boiling
| Evaporation | Boiling |
|---|---|
| Occurs at the surface of the liquid | Occurs throughout the entire liquid |
| Occurs below boiling point | Occurs at or above boiling point |
| Requires external heat or energy | Requires continuous external heat |
| Formation of bubbles on the surface | Bubbles form throughout the liquid |
| Gradual and continuous | Rapid and continuous |
Latent heat of fusion and vaporization
Latent Heat of Fusion: This is the amount of heat energy required to change a substance from a solid to a liquid state at its melting point, without changing its temperature. In simpler terms, it's the energy needed to break the bonds holding the particles in a solid, allowing them to transition into a liquid.
Latent Heat of Vaporization: This is the amount of heat energy required to change a substance from a liquid to a vapor (gas) state at its boiling point, without changing its temperature. In simpler terms, it's the energy needed to overcome the attractive forces between liquid particles and transform them into vapor.